No. It's a long-standing myth.
No, the Great Wall is not visible to the naked eye from space in any meaningful sense. It is very long but only about 5 to 9 meters wide, and it blends into the terrain around it.
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Visibility depends on width and contrast, not length. At low Earth orbit altitudes of about 400 km, a structure just a few meters wide that matches its surroundings falls below what the human eye can resolve. Astronauts have consistently reported this, including Chinese astronaut Yang Liwei. A few astronauts claim to have glimpsed it under ideal lighting conditions, but these accounts are rare and unverified, and even then it is not distinguishable the way many other human-made features are. From the Moon it is certainly not visible. So the popular claim is false.
- China's first astronaut, Yang Liwei, said in 2003 that he could not see the Great Wall from orbit.
- The wall is mostly under 10 meters wide and is similar in color to the surrounding land.
- Astronauts on the ISS (about 400 km up) have reported that it is extremely hard or impossible to pick out without aid, and photos that show it were taken with zoom lenses.
- Highways, airports and city lights are much easier to see from low Earth orbit.
- The myth predates spaceflight, appearing in print in the 1930s, before anyone had been to space.